Graphene-enhanced membranes for improved proton exchange membrane fuel cells

Background

Proton Exchange Membrane Fuel Cells (PEMFCs) are integral to advancing clean energy, offering high efficiency and low emissions for automotive power and stationary energy generation. However, widespread adoption of PEMFCs is hindered by several performance and durability challenges. Among these, hydrogen crossover—where hydrogen molecules permeate through the membrane—results in reduced fuel efficiency, safety risks, and compromised energy output.

Existing membranes often fail to balance proton conductivity with hydrogen selectivity, which reduces overall performance. Additionally, membrane degradation under operational stress shortens the lifespan of fuel cells and increases maintenance costs. These limitations underscore the urgent demand for innovative solutions to improve performance, durability, and scalability, ensuring PEMFCs can meet growing energy needs reliably and sustainably.

Technology overview

This technology significantly enhances PEMFC performance by incorporating defect-engineered graphene with Gore SELECT membranes to create an advanced fuel cell membrane. The process uses commercially available graphene on copper foil, treated with UV-Ozone to introduce controlled defects that improve selective transport properties. The treated graphene is laminated onto a Gore SELECT PEM, forming a robust sandwich structure with superior characteristics. Gas diffusion electrodes with platinum catalysts on Vulcan are integrated into the final membrane electrode assembly.

This novel design achieves a 27% increase in hydrogen/proton selectivity, a 24% reduction in hydrogen crossover, and up to a 10% boost in current output at 0.6V, alongside a 39% slower degradation rate compared to conventional membranes. The advanced membranes sustain high performance even after 100-hour accelerated stress testing, confirming their durability and reliability.

Raman spectroscopy verifies the controlled defect introduction in the graphene, which significantly improves proton transport while reducing hydrogen permeation. This improved performance is especially evident in the critical operational voltage range of 0.6V to 0.7V, where fuel cell efficiency is paramount.

The technology is compatible with existing manufacturing processes, enabling scalable production with minimal infrastructure changes. By addressing the limitations of traditional membranes, this innovation extends PEMFC lifespan and reduces the likelihood of failure, positioning it as a major advancement in clean energy technology.

Benefits

  • A 27% improvement in hydrogen/proton selectivity minimizes hydrogen crossover, increasing fuel efficiency and operational safety.
  • Slower degradation rates ensure longer operational life and lower maintenance costs.
  • Boosts in current output and sustained efficiency under stress testing ensure reliable performance.
  • Compatibility with existing manufacturing infrastructures enables seamless industry adoption.

Applications

  • Automotive fuel cells
  • Fuel cell manufacturers
  • Membrane producers
  • Hydrogen energy storage
  • Stationary power systems